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The coupling of aryl halides with copper at very high temperature is called the Ullmann reaction, which is of broad scope and has been used to prepare many symmetrical biaryls. However, when a mixture of two different aryl halides is used, there are three possible biaryl products.

The coupling of aryl halides with copper at very high temperature is called the Ullmann reaction, which is of broad scope and has been used to prepare many symmetrical biaryls. However, when a mixture of two different aryl halides is used, there are three possible biaryl products.


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